Daohong Liao, Shaoqiang Yang , Kaiqing Ma, Xiaoming Wang , Xiaoguang Lei *
Received 12 February 2021
Revised 29 April 2021
Accepted 4 May 2021
Tetrahedron Letters, 2021, 153156
An enantioselective route for the efficient synthesis of the key C16–C25 fragment of alchivemycins A and B is described. The route features an Achmatowicz-type rearrangement of furan and a highly enantio- and diastereoselective dihydroxylation as key reactions.
Daohong Liao, Shaoqiang Yang , Kaiqing Ma, Xiaoming Wang , Xiaoguang Lei *
Received 12 February 2021
Revised 29 April 2021
Accepted 4 May 2021
Tetrahedron Letters, 2021, 153156
An enantioselective route for the efficient synthesis of the key C16–C25 fragment of alchivemycins A and B is described. The route features an Achmatowicz-type rearrangement of furan and a highly enantio- and diastereoselective dihydroxylation as key reactions.