张文雄

学术简历:

• 2021.01-至今PI，77779193永利集团无机所工作，博雅特聘教授
• 2018.01-2020.12，77779193永利集团有机所工作，博雅特聘教授
• 2016.08-2017.12，77779193永利集团有机所工作，教授
• 2009.10-2009.12，日本理化学研究所客座研究员
• 2007.10-2016.07，77779193永利集团有机所工作，副教授
• 2004.11-2007.09，日本理化学研究所博士后
• 2004.01-2004.03，日本北海道大学JST研究员
• 2002.10-2004.10，77779193永利集团博士后
• 1999.09-2002.09，南开大学77779193永利集团，理学博士
• 1996.09-1999.06，广西师范大学化学与药学学院，理学硕士
• 1992.09-1996.07，湖南师范大学化学化工学院，化学教育学士

获奖情况:

• 2019年获宝钢优秀教师奖
• 2019年获永利集团优秀博士学位论文指导教师
• 2017年获国家杰出青年科学基金
• 2016年获杨芙清王阳元院士优秀教学科研奖
• 2015年获Thieme Chemistry Journals Award

科研领域及兴趣：

稀土是我国重要的战略资源，也是不可再生资源。稀土元素因其独特的4f电子结构和特殊的物理和化学性质，无论从基础研究还是应用研究的角度都具有重要意义。稀土金属有机化合物在小分子和惰性化学键活化，烯烃聚合，有机合成催化等领域扮演了重要的角色，但反应类型、选择性和底物范围同其它过渡金属有机化合物形成互补。稀土金属有机杂环化合物，与主族和过渡金属有机杂环化合物的研究相比，鲜有报道。本课题组的研究思路：建立简单、高效的合成方法，创建新的稀土金属有机杂环；结构表征及阐明其成键模式，并发现其新的反应性和催化功能；通过反应活性中间体的分离和结构表征，结合计算化学，阐明反应机制；基于发现的新反应，结合国家需求，开发关键化学化工产品的新工艺。主要研究兴趣包括：

1. 稀土金属有机杂环化学；
2. 稀土或其它金属促进的白磷直接合成有机膦的新方法和技术。

代表性论文：

(*: Corresponding author, #: Authors contributed equally)

1. Yu Zheng,# Chang-Su Cao,# Wangyang Ma,# Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi, 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins, J. Am. Chem. Soc. 2020,142, 10705-10714.
2. Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi, Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction, Chem. Soc. Rev. 2020, 49, 5810-5849.
3. Nan Li,# Botao Wu,# Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*, Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction, Angew. Chem. Int. Ed. 2020, 59, 8868-8872.
4. Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi, Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity, J. Am. Chem. Soc. 2019, 141, 20547-20555.
5. Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation, J. Am. Chem. Soc. 2019, 141, 8773-8777.
6. Shanshan Du,# Jimin Yang,# Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds, J. Am. Chem. Soc. 2019, 141, 6843-6847.
7. Jianhao Yin,# Jiapeng Li,# Gao-Xiang Wang,# Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*, Dinitrogen Functionalization Affording Chromium Hydrazido Complex, J. Am. Chem. Soc. 2019, 141, 4241-4247.
8. Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang*, Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes, Angew. Chem. Int. Ed. 2017, 56, 15886-15890.
9. Baosheng Wei, Liang Liu, Wen-Xiong Zhang*, and Zhenfeng Xi, Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4[O] Inverse Crown Ether Complex, Angew. Chem. Int. Ed. 2017, 56, 9188-9192.
10. Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi*, Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation, J. Am. Chem. Soc. 2017, 139, 13688-13691.
11. Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*, Spiro Metalla-aromatics of Pd, Pt, Rh: Synthesis and Characterization, J. Am. Chem. Soc. 2017, 139, 5039-5042.
12. Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes, Chem. Sci. 2017, 8, 6852-6856.
13. Wangyang Ma,# Chao Yu,# Tianyang Chen,# Ling Xu, Wen-Xiong Zhang*, and Zhenfeng Xi, Metallacyclopentadienes: Synthesis, Structure and Reactivity, Chem. Soc. Rev. 2017, 46, 1160-1192.
14. Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts, Angew. Chem. Int. Ed. 2016, 55, 14762-14765.
15. Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi, Direct Synthesis of Phospholyl Lithium from White Phosphorus, Angew. Chem. Int. Ed. 2016, 55, 9187-9190.
16. Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang*, and Zhenfeng Xi, Transition-Metal-Catalyzed Cleavage of C–N Single Bonds, Chem. Rev. 2015,115, 12045-12090.
17. Yang Wang, Yue Chi, Wen-Xiong Zhang*, and Zhenfeng Xi*, Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides, J. Am. Chem. Soc. 2012, 134, 2926-2929.
18. Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi*, Zirconocene and Si-Tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis, Acc. Chem. Res. 2011, 44, 541-551.
19. Yang Wang, Wen-Xiong Zhang*, Zitao Wang, and Zhenfeng Xi*, Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and their Selenium and Tellurium Derivatives by Convergent Tandem Annulation, Angew. Chem. Int. Ed.2011, 50, 8122-8126.
20. Zitao Wang, Yang Wang, Wen-Xiong Zhang*, Zhaomin Hou, and Zhenfeng Xi*, Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides, J. Am. Chem. Soc. 2009, 131, 15108-15109.