Large increase in external quantum efficiency by dihedral angle tuning in a sky-blue thermally activated delayed fluorescence emitter.
Huang, W.†,*; Einzinger, M.†,*; Maurano, A.; Zhu, T.; Tiepelt, J.; Yu, C.; Chae, H.-S.; Van Voorhis, T.; Baldo, M. A.; Buchwald, S. L.
Adv. Optical Mater. 2019, 7, 1900476.
Molecular design of deep blue thermally activated delayed fluorescence materials employing a homoconjugative triptycene scaffold and dihedral angle engineering.
Huang, W.; Einzinger, M.; Zhu, T.; Chae, H.-S.; Jeon, S.; Lee, S.-Y.; Ihn, S.-G.; Sim, M.; Kim, S.; Su, M.; Teverovskiy, G.; Wu, T.; Van Voorhis, T.; Swager, T. M.; Baldo, M. A.; Buchwald, S. L.
Chem. Mater. 2018, 30, 1462–1466.
Reduction of diphenylacetylene mediated by rare-earth ferrocene diamide complexes.
Brosmer, J. L.; Huang, W.; Diaconescu, P. L.*
Organometallics 2017, 36, 4643–4648.
Aromatic C–F bond activation by rare-earth metal complexes.
Huang, W.; Diaconescu, P. L.*
Organometallics 2017, 36, 89–96.
Reactivity and properties of metal complexes enabled by flexible and redox-active ligands with a ferrocene backbone.
Huang, W.; Diaconescu, P. L.*
Inorg. Chem. 2016, 55, 10013–10023.
Palladium catalyzed N-arylation of iminodibenzyls and iminostilbenes with aryl and hetero‐aryl halides.
Huang, W.; Buchwald, S. L.*
Chem. Eur. J. 2016, 22, 14186–14189.
Design of efficient molecular organic light-emitting diodes by a high-throughput virtual screening and experimental approach.
Gómez-Bombarelli, R.; Aguilera-Iparraguirre, J.; Hirzel, T.; Duvenaud, D.; Maclaurin, D.; Blood-Forsythe, M.; Chae, H.-S.; Einzinger, M.; Ha, D.-G.; Wu, T.; Markopoulos, G.; Jeon, S.; Kang, H.; Miyazaki, H.; Numata, M.; Kim, S.; Huang, W.; Hong, S.-I.; Baldo, M. A.*; Adams, R.*; Aspuru-Guzik, A.*
Nat. Mater. 2016, 15, 1120–1127.
Chapter Two: C–H Bond activation of hydrocarbons mediated by rare-earth metals and actinides: beyond σ-bond metathesis and 1,2-addition
In: Pérez, Pedro J., Editor(s), Advances in Organometallic Chemistry
Huang, W.; Diaconescu, P. L.*
Academic Press 2015, 64, 41–75, ISSN 0065-3055, ISBN 9780128029404.
In situ synthesis of rare-earth metal complexes supported by ferrocene diamide ligand: extension to redox active lanthanide ions.
Huang, W.; Brosmer, J. L.; Diaconescu, P. L.*
New J. Chem. 2015, 39, 7696–7702.
Rare-earth metal π-complexes of reduced arenes, alkenes, and alkynes: bonding, electronic structure and comparison with actinides and other highly electropositive metals.
Huang, W.; Diaconescu, P. L.*
Dalton Trans. 2015, 44, 15360–15371.
Tetraanionic biphenyl lanthanide complexes as single-molecule magnets.
Huang, W. †; Le Roy, J. J. †; Khan, S. I.; Ungur, L.*; Murugesu, M.*; Diaconescu, P. L.*
Inorg. Chem. 2015, 54, 2374–2382.
Bimetallic cleavage of aromatic C–H bonds by rare-earth-metal complexes.
Huang, W.; Dulong, F.; Khan, S. I.; Cantat, T.*; Diaconescu, P. L.*
J. Am. Chem. Soc. 2014, 136, 17410–17413.
Rare earth arene-bridged complexes obtained by reduction of organometallic precursors.
Huang, W.; Diaconescu, P. L.*
Handbook on the Physics and Chemistry of Rare Earths 2014, 45, 261–329.
Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies.
Huang, W.; Abukhalil, P. M.; Khan, S, I.; Diaconescu, P. L.*
Chem. Commun. 2014, 50, 5221–5223.
P4 Activation by lanthanum and lutetium naphthalene complexes supported by a ferrocene diamide ligand.
Huang, W.; Diaconescu, P. L.*
Eur. J. Inorg. Chem. 2013, (22–23), 4090–4096.
Synthesis and characterization of paramagnetic lanthanide benzyl complexes.
Huang, W.; Upton, B. M.; Khan, S. I.; Diaconescu, P. L.*
Organometallics 2013, 32, 1379–1386.
A six-carbon, 10π-electron aromatic system supported by group 3 metals.
Huang, W.; Dulong, F.; Wu, T.; Khan, S. I.; Miller, J. T.; Cantat, T.; Diaconescu, P. L.*
P4 activation by group 3 metal arene complexes.
Huang, W.; Diaconescu, P. L.*
Chem. Commun. 2012, 48, 2216–2218.
Visible-light-induced reversible C–C bond formation of an imidazole-derived scandium complex.
Huang, W.; Diaconescu, P. L.*
Inorg. Chim. Acta 2012, 380, 274–277.
Inverted sandwiches of scandium arene complexes supported by a ferrocene diamide ligand.
Huang, W.; Khan, S. I.; Diaconescu, P. L.*
J. Am. Chem. Soc. 2011, 133, 10410–10413.
Transmetalation reactions of a scandium complex supported by a ferrocene-diamide ligand.
Huang, W.; Carver, C. T.; Diaconescu, P. L.*
Inorg. Chem. 2011, 50, 978–984.
Group 3 metal complexes of radical-anionic 2,2'-bipyridyl ligands.
Williams, B. N.; Huang, W.; Miller, K. L.; Diaconescu, P. L.*
Inorg. Chem. 2010, 49, 11493–11498.