The key aspect of molecular engineering towards functional low dimensional nanomaterial is the controlled construction of well-ordered molecular nanostructure, in terms of shapes, size, composition, symmetry, chirality, etc.. In principle, the molecular nanostructure can be classified into two categories according to the interactions between molecules: (1) structures formed by week non-covalent interactions like hydrogen bond, halogen bond, van der Waals interactions, coordinations; (2) structures formed by covalent bonds. The formation of these two types of nanostructure on the surface involves processes of molecular self-assembling and surface reaction, respectively. Another focus is on the utilization of self-assembly strategy to mediate the regioselectivity, site-selectivity, reaction pathway of surface reactions. We are interested in the basic scientific question about how self-assembly would affect the reactivity of individual molecule, the electronic property of the substrate, and the construction of novel covalent nanostructure. |