柴正祺(2024年博士毕业生)

姓名:柴正祺
专业:有机化学
研究方向:稀土金属有机化学
电子邮件jxtxczq@pku.edu.cn
 
教育背景
2019.9 - 2024.6   77779193永利集团,博士研究生
                             导师:席振峰教授、张文雄教授
2015.9 - 2019.7   77779193永利集团,本科生
                             导师:席振峰教授、张文雄教授
2012.9 - 2015.6   浙江省杭州第二中学
 
工作经历
2024.12 - 至今     新加坡国立大学化学系,博士后
                             导师:葛少中教授
2024.6  2024.12 77779193永利集团,临时博士后
                            导师:张文雄教授
 
发表论文

1. Zhengqi Chai, and Wen-Xiong Zhang*, Dicarbanion Compounds: The Bridge between Organometallic Reagents and Mononuclear Heterocycles, Organometallics 2022, 41, 3455–3477. (Review)

2. Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Rare-Earth Metallacycloheptatrienes: Synthesis, Structure and Reactivity, Organometallics 2023, 42, XXXXX–XXXXX

3. Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, and Wen-Xiong Zhang*, Cascade C−H Activation and Two C−C Bond Forming in Reaction of Azalutetacyclopentadiene with 2-Methylbenzonitriles, Chem. Eur. J. 2024, 30, e20240231.

4. Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, and Wen-Xiong Zhang*, sp2-sp Cross-Carbanion Coupling at a Rare-Earth Center Leading to the Formation of Carbon-Carbon Double Bonds, Inorg. Chem. Front. 202411, 2312-2318.

5. Ze-Jie Lv, Zhengqi Chai, Miaomiao Zhu, Junnian Wei, and Wen-Xiong Zhang*, Selective Coupling of Lanthanide Metallacyclopropenes and Nitriles via Azametallacyclopentadiene and η2-Pyrimidine Metallacycle, J. Am. Chem. Soc. 2021, 143, 9151–9161. (Cover Paper)

6. Ze-Jie Lv, Miaomiao Zhu, Wei Liu, Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Reactivity of Lutetacyclopropene toward Benzyl, Benzoyl, and Trimethylsilyl Nitriles Affording Diversified Lutetium Complexes, Organometallics 2021, 40, 3992–3998.

7. Ze-Jie Lv, Wei Liu, Miaomiao Zhu, Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Insertion Chemistry of Lutetacyclopropene toward Unsaturated C−O/C−N Bonds, Chem. Eur. J. 2021, 27, 16498–16504.

8. Jingyuan Hu, Zhengqi Chai, Wei Liu, Zhe Huang, Junnian Wei, and Wen-Xiong Zhang*, Phosphafluorenyl Lithiums: Direct Synthesis from White Phosphorus, Structure and Diversified Synthons, Sci. China Chem. 2022, 65, 322–327.

9. Miaomiao Zhu#, Zhengqi Chai#, Tianyu Li, Junnian Wei, Ze-Jie Lv*, and Wen-Xiong Zhang*, Selective C−C Coupling of Two Nitriles Affording Rare-Earth Diazametallacyclopentadienes: Synthesis, Cooperative Reactivity and Mechanistic Studies, Inorg. Chem. Front. 202310, 4569–4577. ( #Authors contributed equally)

10. Miaomiao Zhu#, Zhengqi Chai#, Ze-Jie Lv#, Tianyu Li, Wei Liu , Junnian Wei, and Wen-Xiong Zhang*, Selective Cleavage of the Strong or Weak C–C Bonds in Biphenylene Enabled by Rare-Earth Metals, J. Am. Chem. Soc. 2023, 145, 6633–6638 ( #Authors contributed equally)

11. Yaqi Zhao, Zhengqi Chai, Qingrui Zeng, and Wen-Xiong Zhang*, Overview of 1,5-Selective Click Reaction of Azides with Alkynes or Their Synthetic EquivalentsMolecules 202328, 1400. (Invited Review)

12. Wei Liu #, Yaqi Zhao #, Wangyang Ma, Zhengqi Chai, Yibo Liang, Ze-Jie Lv, Ling Xu, Junnian Wei, and Wen-Xiong Zhang*Cross-Carbanion Coupling at a Rare-Earth Center, Cell Rep. Phys. Sci. 2023, 4, 101479. ( #Authors contributed equally)

13. Jingyuan Hu, Zhengqi Chai, Wei Liu, Junnian Wei, Ze-Jie Lv and Wen-Xiong Zhang*, Direct and Chlorine-Free Synthesis of Phosphafluorenes or Their Oxides from White Phosphorus, Green Synth. Catal. 2023, 4, 330–333.

14. Miaomiao Zhu, Tianyu Li, Zhengqi Chai, Junnian Wei, Ze-Jie Lv*, and Wen-Xiong Zhang*, Diversified Two-Electron Reduction for Trivalent Scandium Complexes with Arene Ligands, Inorg. Chem. Front. 202310, 630–637.

15. Dajiang Huang#, Wei Liu#, Yu Zheng, Rui Feng, Zhengqi Chai, Junnian Wei, and Wen-Xiong Zhang*, Nonplanar Aromaticity of Dinuclear Rare-Earth Metallacycles, J. Am. Chem. Soc. 2024, 146, 15609–15618. ( #Authors contributed equally)

16. Wufeng Chen#, Ni Zhang#, Zhengqi Chai, Junnian Wei, Gen Luo* and Wen-Xiong Zhang*, Rare-Earth-Catalyzed Regiodivergent Hydrosilylation of Aryl Alkenes, ACS Catal202414, 5612-5620. ( #Authors contributed equally)